Home Safety at work Hazardous substances

UN Hazard classes and pictograms

PictogramClassDescription
1Explosive

Includes TNT, ammunition, rockets, fireworks and other explosive substances listed in the Australian Explosives Code.

Contains 6 divisions to classify different blast levels.
2.1Flammable gas

Gas that ignites on contact with an ignition source.

Includes acetylene, hydrogen, and propane.
2.2Non-flammable non-toxic gas

Gas that is neither flammable nor poisonous.

Includes nitrogen, neon, and carbon dioxide.
2.3Poisonous gas

Gas that is liable to cause death or serious injury to human health if inhaled.

Includes fluorine, chlorine, and hydrogen cyanide.
3Flammable liquid

Liquid that is easily ignited by a source of ignition.

Includes petrol, kerosene, diesel, turpentine and paint thinners.
4.1Flammable solid

Solid substance that is easily ignited and readily combustible.

Includes nitrocellulose, magnesium, firelighters and matches.
4.2Spontaneously combustible solid

Solid substance that can ignite spontaneously.

Includes aluminium alkyl and white phosphorus.
4.3Dangerous when wet

Solid substance that emits a flammable gas when wet, or reacts violently with water.

Includes sodium, calcium, potassium and calcium carbide.
5.1Oxidising agent

Substance that may not be combustible by itself, but may produce oxygen which increases the risk and intensity of a fire occurring in other materials.

Includes ammonium nitrate and hydrogen peroxide.
5.2Organic peroxide oxidising agent

Organic peroxide, either in liquid or solid form, which may react dangerously with other substances.

Includes benzoyl peroxides and cumene hydroperoxide.
6.1Poison

Toxic substance which is liable to cause death or serious injury if inhaled, swallowed or absorbed through the skin.

Includes cyanide and mercuric chloride.
6.2Biohazard

Infectious substance likely to cause death or injury if swallowed, inhaled or brought into contact with the skin.

Includes bacteria, viruses, parasites and fungi.
7Radioactive

Substance that emits ionizing radiation.

Includes uranium and plutonium.
8Corrosive

Substance that can dissolve living tissue or severely corrode certain metals.

Includes: acids, such as sulfuric acid and hydrochloric acid, and alkalis, such as potassium hydroxide and sodium hydroxide.
9Miscellaneous

Hazardous substance that does not fall into any of the other categories.

Includes asbestos, air-bag inflators and dry ice.
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